Formation of dynamic aggregates in water by cucurbit[5]uril capped with gold nanoparticles

被引:119
作者
Lee, Tung-Chun [1 ]
Scherman, Oren A. [1 ]
机构
[1] Univ Cambridge, Dept Chem, Melville Lab Polymer Synth, Cambridge CB2 1EW, England
关键词
SIZE; CUCURBITURIL; MOLECULES; GUEST;
D O I
10.1039/b925051d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Supramolecular capping of cucurbit[5]uril (CB[5]) by gold nanoparticles has been achieved via a facile reduction of an aqueous solution of HAuCl4 by NaBH4 in the presence of various amounts of CB[5]. The resultant assemblies were very stable in solution, and were found to form dynamic aggregates consisting of a controllable ratio of singly and doubly capped CB[5].
引用
收藏
页码:2438 / 2440
页数:3
相关论文
共 26 条
[1]   A general and efficient method to form self-assembled cucurbit[n]uril monolayers on gold surfacest [J].
An, Qi ;
Li, Guangtao ;
Tao, Chengan ;
Li, Yan ;
Wu, Yiguang ;
Zhang, Weixia .
CHEMICAL COMMUNICATIONS, 2008, (17) :1989-1991
[2]   SYNTHESIS OF THIOL-DERIVATIZED GOLD NANOPARTICLES IN A 2-PHASE LIQUID-LIQUID SYSTEM [J].
BRUST, M ;
WALKER, M ;
BETHELL, D ;
SCHIFFRIN, DJ ;
WHYMAN, R .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (07) :801-802
[3]   Core-shell-corona Au-micelle composites with a tunable smart hybrid shell [J].
Chen, Xi ;
An, Yingli ;
Zhao, Dongyun ;
He, Zhenping ;
Zhang, Yan ;
Cheng, Jing ;
Shi, Linqi .
LANGMUIR, 2008, 24 (15) :8198-8204
[4]   Well-Aligned Single-Crystalline GaN Nanocolumns and Their Field Emission Properties [J].
Chen, Zhuo ;
Cao, Chuanbao ;
Li, Wai Sang ;
Surya, Charles .
CRYSTAL GROWTH & DESIGN, 2009, 9 (02) :792-796
[5]   Gold nanoparticles in organic capsules:: A supramolecular assembly of gold nanoparticles and cucurbituril [J].
Corma, Avelino ;
Garcia, Hermenegildo ;
Montes-Navajas, Pedro ;
Primo, Ana ;
Calvino, Jose Juan ;
Trasobares, Susana .
CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (22) :6359-6364
[6]  
El Haouaj M, 2001, J CHEM SOC PERK T 2, P2104
[7]   CONTROLLED NUCLEATION FOR REGULATION OF PARTICLE-SIZE IN MONODISPERSE GOLD SUSPENSIONS [J].
FRENS, G .
NATURE-PHYSICAL SCIENCE, 1973, 241 (105) :20-22
[8]   Determination of size and concentration of gold nanoparticles from UV-Vis spectra [J].
Haiss, Wolfgang ;
Thanh, Nguyen T. K. ;
Aveyard, Jenny ;
Fernig, David G. .
ANALYTICAL CHEMISTRY, 2007, 79 (11) :4215-4221
[9]   Controlled Step Growth of Molecularly Linked Gold Nanoparticles: From Metallic Monomers to Dimers to Polymeric Nanoparticle Chains [J].
Hussain, Irshad ;
Brust, Mathias ;
Barauskas, Justas ;
Cooper, Andrew I. .
LANGMUIR, 2009, 25 (04) :1934-1939
[10]   Encapsulation of N2, O2, methanol, or acetonitrile by decamethylcucurbit[5]uril(NH4+)2 complexes in the gas phase:: Influence of the guest on "lid" tightness [J].
Kellersberger, KA ;
Anderson, JD ;
Ward, SM ;
Krakowiak, KE ;
Dearden, DV .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (45) :11316-11317