Generation of Melamine Polymer Condensates upon Hypergolic Ignition of Dicyanamide Ionic Liquids

被引：40

作者：

Chingin, Konstantin ^{[1
]}

Perry, Richard H. ^{[1
]}

Chambreau, Steven D. ^{[2
]}

Vaghjiani, Ghanshyam L. ^{[2
]}

Zare, Richard N. ^{[1
]}

机构：

[1] Stanford Univ, Dept Chem, Stanford, CA 94305 USA

[2] USAF, Res Lab, AFRL RZSP, Edwards AFB, CA 93524 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 37期

基金：

瑞士国家科学基金会;

关键词：

dicyanamides; hypergolic ignition; ionic liquids; melamines; triazines; GRAPHITIC CARBON NITRIDE; RAY-POWDER DIFFRACTOMETRY; ENERGETIC MATERIALS; THERMAL-DECOMPOSITION; CRYSTAL-STRUCTURES; MASS-SPECTROMETER; ISOCYANIC ACID; CONVERSION; MELEM; PROPELLANTS;

D O I：

10.1002/anie.201101247

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of dicyanamide ionic liquids with nitric acid results in hypergolic ignition and the formation of a stable precipitate. The precipitate consists of cyclic triazines, including melamine and its polymers, such as melam and melem (see scheme). This study introduces a novel approach to the synthesis of cyclic azines without resorting to high temperatures and pressures. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：8634 / 8637

页数：4

共 55 条

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