Synthesis and crystal structure of two members of a new type of layered compound: Copper(II) hydroxyphosphonates

被引：39

作者：

Drumel, S

Janvier, P

BujoliDoeuff, M

Bujoli, B

机构：

[1] CNRS,INST MAT NANTES,UM 0110,F-44072 NANTES 03,FRANCE

[2] CNRS,URA 475,SYNTH ORGAN LAB,F-44072 NANTES 03,FRANCE

来源：

INORGANIC CHEMISTRY | 1996年 / 35卷 / 20期

关键词：

D O I：

10.1021/ic960411+

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two original layered copper(II) hydroxyphosphonates Cu-2.5(O3P(CH2)(2)NH3)(OH)(2)(SO4) (monoclinic P2(1)/n (No. 14), a = 5.442(1) Angstrom, b = 20.570(4) Angstrom, c = 8.529(2) Angstrom, beta = 93.18(3)degrees, Z = 4) and Cu-2(O3P(CH2)(2)NH2)(OH)(NO3). H2O (monoclinic P2(1) (No. 4), a = 8.392(2) Angstrom, b = 6.132(1) Angstrom, c = 9.097(2) Angstrom, beta = 104.11(3)degrees, Z = 2) were prepared from copper sulfate or nitrate, (2-aminoethyl)phosphonic acid, and sodium hydroxide in water. In both cases, the anion of the starting copper salt was retained in the structure. For the first compound, the sulfate groups were part of the layer, while, for the second, the nitrate groups were present in the interlayer space, in a manner similar to that observed in layered double hydroxides.

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页码：5786 / 5790

页数：5

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