Metal-organic frameworks based on iron oxide octahedral chains connected by benzenedicarboxylate dianions

被引：228

作者：

Whitfield, TR

Wang, XQ ^{[1
]}

Liu, LM

Jacobson, AJ

机构：

[1] Univ Houston, Dept Chem, Houston, TX 77204 USA

[2] Univ Houston, Ctr Mat Chem, Houston, TX 77204 USA

来源：

SOLID STATE SCIENCES | 2005年 / 7卷 / 09期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/j.solidstatesciences.2005.03.007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three new iron benzenedicarboxylates have been synthesized by solvothermal techniques, and their structures determined from single crystal X-ray data: Fe(OH)(BDC)(py)(0.85) (1), Fe(BDC)(DMF) (2), and Fe(BDC)(py)(0.42)(DMF)(0.25) (3) (BDC = 1,4-benzenedicarboxylate, py = pyridine, DMF = N,N-dimethylformamide). Compounds I and 2 are the Fe(III)- and Fe(II)-structural analogs of the known Cr benzenedicarboxylate compound (MIL-53). Both contain trans comer-sharing FeO6 octahedral chains connected by benzenedicarboxylate dianions. Compound 3 contains chains of iron oxygen octahedra that share both corners and edges. Each chain is linked by BDC to six other chains to form a three-dimensional framework. Crystal data: 1, space group I2/a, a = 6.889(2), b = 11.073(3), c = 18.280(6) angstrom, beta = 92.6(1)degrees; 2, space group Pn2(1)a, a = 19.422(2), b = 7.3022(5), c = 8.8468(7) angstrom; 3, space group P2(1)/n, a = 9.234(2), b = 17.243(3), c = 9.978(2) angstrom-beta = 93.9(1)degrees. (c) 2005 Elsevier SAS. All rights reserved.

引用

页码：1096 / 1103

页数：8

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