Pressure effect on crystallization kinetics in Zr46.8Ti8.2Cu7.5Ni10Be27.5 bulk glass

被引:19
作者
Jiang, JZ
Gerward, L
Xu, YS
机构
[1] Tech Univ Denmark, Dept Phys, DK-2800 Lyngby, Denmark
[2] Univ Bayreuth, Bayer Geoinst, D-95440 Bayreuth, Germany
关键词
D O I
10.1063/1.1527227
中图分类号
O59 [应用物理学];
学科分类号
摘要
Crystallization kinetics of a Zr46.8Ti8.2Cu7.5Ni10Be27.5 bulk glass in the supercooled liquid region have been investigated by performing in situ high-temperature and high-pressure x-ray diffraction measurements using synchrotron radiation. A pressure-time-temperature-transformation diagram, describing the onset of crystallization as a function of time during isothermal annealing under pressure, is presented. Different pressure dependences of crystallization kinetics in the temperature range for the glass have been observed and further be explained by a model of competing processes of the thermodynamic potential barrier of nucleation and the diffusion activation energy under pressure. (C) 2002 American Institute of Physics.
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页码:4347 / 4349
页数:3
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