Applicability and mathematical verification of the reactivity-selectivity principle in the oxidation of thioanisoles by oxo(salen)manganese(V) complexes

被引：57

作者：

Chellamani, A ^{[1
]}

Alhaji, NMI ^{[1
]}

Rajagopal, S ^{[1
]}

机构：

[1] MADURAI KAMARAJ UNIV,SCH CHEM,MADURAI 625021,TAMIL NADU,INDIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1997年 / 02期

关键词：

D O I：

10.1039/a604602i

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The second-order rate constants for the oxidation of various para-substituted thioanisoles with substituted oxo(salen)manganese(v) complexes have been measured spectrophotometrically in acetonitrile at 25 degrees C, Electron-withdrawing substituents in thioanisoles and electron-releasing substituents in oxo(salen)Mn-v complexes decrease the rate of oxidation, Correlation analyses show the presence of an inverse relationship between reactivity and selectivity in the reactions of various thioanisoles with a given oxo(salen)Mn-v complex and also in various oxo(salen)Mn-v complexes with a given thioanisole, Mathematical treatment of the results has also been carried out.

引用

页码：299 / 302

页数：4

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