Synthesis and magnetic properties of nickel(II)-gadolinium(III) and copper(II)-gadolinium(III) complexes of a compartmental ligand, N,N'-bis(3-hydroxysalicylidene)-2-aminobenzylamine

被引：9

作者：

Sakamoto, M

Kumagai, M

Sakiyama, H

Nishida, Y

Sadaoka, Y

Matsumoto, A

Ohba, M

Okawa, H

机构：

[1] EHIME UNIV,FAC ENGN,DEPT MAT SCI & ENGN,BUNKYO KU,MATSUYAMA,EHIME 79077,JAPAN

[2] EHIME UNIV,FAC EDUC,CHEM LAB,BUNKYO KU,MATSUYAMA,EHIME 79077,JAPAN

[3] KYUSHU UNIV,FAC SCI,DEPT CHEM,HIGASHI KU,FUKUOKA 81281,JAPAN

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1997年 / 27卷 / 04期

关键词：

D O I：

10.1080/00945719708000210

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Nickel(II)-gadolinium(III), (NiGd(dhbabza)(NO3(H2O)), and copper(II)-gadolinium(III), (CuGd(dhbabza)(NO3(H2O)(3)), complexes of a dinucleating ligand, H(4)dhbabza, were synthesized and characterized, and their magnetic properties were investigated, where H(4)dhbabza denotes N,N'-bis(3-hydroxysalicylidene)-2-aminobenzylamine. Cryomagnetic measurements revealed that the intermolecular antiferromagnetic interaction is operating In the Ni(II)-Gd(III) complex, whereas the ferromagnetic spin-spin interaction is operating between Cu(II) and Gd(III) ions in the Cu(II)-Gd(III) complex.

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页码：567 / 575

页数：9

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