Catalyst-Free Synthesis of Oligoanilines and Polyaniline Nanofibers Using H2O2

被引：86

作者：

Surwade, Sumedh P. ^{[1
]}

Agnihotra, Srikanth Rao ^{[1
]}

Dua, Vineet ^{[1
]}

Manohar, Neha ^{[1
]}

Jain, Sujit ^{[1
]}

Ammu, Srikanth ^{[1
]}

Manohar, Sanjeev K. ^{[1
]}

机构：

[1] Univ Massachusetts, Dept Chem Engn, Lowell, MA 01854 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 35期

关键词：

CONDUCTING POLYANILINE; POLYMERIZATION; ANILINE; OXIDATION; PEROXIDE; ROUTE;

D O I：

10.1021/ja905014e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Nanofibers of polyaniline and oligoanilines of controlled molecular weight, e.g., tetraaniline, octaaniline, and hexadecaaniline, are synthesized using a versatile high ionic strength aqueous system that permits the use of H2O2 with no added catalysts as a mild oxidizing agent. Films of oligoanilines deposited on plastic substrates show a robust and reversible chemiresistor response to NO2 vapor at room temperature in ambient air (100-5 ppm).

引用

页码：12528 / +

页数：4

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