Thienyl-Appended porphyrins: Synthesis, photophysical and electrochemical properties, and their applications

被引：74

作者：

Boyle, Nicola M. ^{[1
]}

Rochford, Jonathan ^{[2
]}

Pryce, Mary T. ^{[1
]}

机构：

[1] Dublin City Univ, Sch Chem Sci, Dublin 9, Ireland

[2] Brookhaven Natl Lab, Dept Chem, Upton, NY 11973 USA

来源：

COORDINATION CHEMISTRY REVIEWS | 2010年 / 254卷 / 1-2期

关键词：

Porphyrin; Thienyl; Photophysical; Electrochemical; Oligothiophene; PHOTOINDUCED ELECTRON-TRANSFER; FULLERENE LINKED TRIADS; ENERGY-TRANSFER; MESO-TETRATHIENYLPORPHYRINS; OPTICAL-PROPERTIES; CYTOCHROME-C; OLIGOTHIOPHENE; POLYMERS; FLUORESCENCE; SPECTRA;

D O I：

10.1016/j.ccr.2009.09.001

中图分类号：

O61 [无机化学];

学科分类号：

070301 [无机化学];

摘要：

This review focuses on the synthesis, photophysical and electrochemical properties of thienyl porphyrins where processes such as electron transfer, energy transfer and electropolymerisation are discussed. The purpose of this review is to examine the influence of the thienyl ring, whether it be directly connected (via mesa and 0 positions) or indirectly connected (via a covalent linker or axial coordination) on the ground and excited state electronic properties of the porphyrin macrocycle. Additionally, the importance of the electronic properties of a bridging oligothiophene between the porphyrin and another centre in supramolecular systems is discussed. Also included are applications of thienyl porphyrins in such areas as catalysis, therapeutics, (opto)electronics and electron-transfer/light-harvesting systems. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：77 / 102

页数：26

共 76 条

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