NMR structural aspects of the chemistry of V, Mo, W polyoxometalates

被引：56

作者：

Fedotov, M. A. ^{[1
]}

Maksimovskaya, R. I. ^{[1
]}

机构：

[1] Russian Acad Sci, Siberian Div, GK Boreskov Inst Catalysis, Novosibirsk, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2006年 / 47卷 / 05期

关键词：

polyoxometalates of V; Mo; W; structure; NMR; O-17; V-51; Mo-95; W-183;

D O I：

10.1007/s10947-006-0413-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The results of structural investigations of vanadium, molybdenum, and tungsten polyoxoanions (PA) by O-17, V-51, Mo-95, W-183, and heteroatom NMR are generalized in this review. NMR spectroscopy possibilities to determine the structure of PA are discussed. NMR data on PA of different structures compositions nuclei are demonstrated.

引用

页码：952 / 978

页数：27

共 112 条

[91]

MAXIMOVSKAIA RI, 1978, DOKL AKAD NAUK SSSR+, V240, P117

[92] O-17 NUCLEAR MAGNETIC-RESONANCE SPECTRA OF CERTAIN OXOMOLYBDENUM(VI) COMPLEXES AND THE INFLUENCE OF THE MULTIPLICITY OF THE MO-O BOND [J].

MILLER, KF ;

WENTWORTH, RAD .

INORGANIC CHEMISTRY, 1979, 18 (04) :984-988

[93] [MoV12O30(μ2-OH)10H2{NiII(H2O)3}4], a highly symmetrical ε-Keggin unit capped with four NiII centers:: Synthesis and magnetism [J].

Müller, A ;

Beugholt, C ;

Kögerler, P ;

Bögge, H ;

Bud'ko, S ;

Luban, M .

INORGANIC CHEMISTRY, 2000, 39 (23) :5176-+

[94]

NOWARTH OW, 1965, J CHEM SOC, P864

[95] STRUCTURE OF K3NA4H2[TBW10O36].20H2O [J].

OZEKI, T ;

TAKAHASHI, M ;

YAMASE, T .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1992, 48 :1370-1374

[96] CRYSTAL STRUCTURE OF SODIUM HEXAMOLYBDOCHROMATE(III) OCTAHYDRATE, NA(CRMO6O24H6).8H2O1 [J].

PERLOFF, A .

INORGANIC CHEMISTRY, 1970, 9 (10) :2228-+

[97]

PETRUKHIN MA, 1989, ZH NEORG KHIM+, V34, P849

[98]

Pope M.T., 1983, HETEROPOLY ISOPOLY O

[99]

PORAIKOSHITS MA, 1974, CRYSTAL CHEM STEREOC

[100]

REDOROV LA, 1989, NMR SPECTROSCOPY INO

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