Au/Ag-Cocatalyzed Aldoximes to Amides Rearrangement under Solvent- and Acid-Free Conditions

被引：142

作者：

Ramon, Ruben S. ^{[1
,2
]}

Bosson, Johann ^{[1
]}

Diez-Gonzalez, Silvia ^{[2
]}

Marion, Nicolas ^{[2
]}

Nolan, Steven P. ^{[1
,2
]}

机构：

[1] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland

[2] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2010年 / 75卷 / 04期

基金：

英国工程与自然科学研究理事会;

关键词：

N-HETEROCYCLIC CARBENES; ONE-POT; BECKMANN REARRANGEMENT; ORGANIC TRANSFORMATIONS; CATALYZED CONVERSION; HYDROXIDE CATALYST; HIGHLY EFFICIENT; GOLD CATALYSIS; NITRILES; DEHYDRATION;

D O I：

10.1021/jo902461a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The gold/silver-cocatalyzed conversion of aldoximes into primary amides is reported. The reaction, which proceeds under neat and acid-free conditions, allows for the conversion of a range of aldoximes, and is a rare example of cooperative catalysis involving well-defined gold species.

引用

页码：1197 / 1202

页数：6

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