Alkoxylated p-phenylenevinylene oligomers: Synthesis and spectroscopic and electrochemical properties.

被引：60

作者：

Ndayikengurukiye, H

Jacobs, S

Tachelet, W

VanderLooy, J

Pollaris, A

Geise, HJ

Claeys, M

Kauffmann, JM

Janietz, S

机构：

[1] UNIV INSTELLING ANTWERP,DEPT CHEM,B-2610 WILRIJK,BELGIUM

[2] UNIV INSTELLING ANTWERP,DEPT PHARMACEUT SCI,B-2610 WILRIJK,BELGIUM

[3] FREE UNIV BRUSSELS,INST PHARM,B-1050 BRUSSELS,BELGIUM

来源：

TETRAHEDRON | 1997年 / 53卷 / 40期

关键词：

D O I：

10.1016/S0040-4020(97)00871-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Twenty-one n-alkoxy substituted phenylenevinylene oligomers were synthesized, varying in size, number and position of the OR groups. IR,MS and solubility data are presented. NMR measurements provided the molecular structure as well as information about conformations and molecular dynamics. UV and of cyclic voltammetric data give correlations of chemical structure (number and position of OR substituents) with separate HOMO and LUMO energies. (C) 1997 Elsevier Science Ltd.

引用

页码：13811 / 13828

页数：18

共 41 条

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