Two 2-fold interpenetrated frameworks showing different topologies based on the isomerous benzenedicarboxylate mixed with a flexible N,N′-type ligand

被引：70

作者：

Chen, Pang-Kuan ^{[1
]}

Che, Yun-Xia ^{[1
]}

Xue, Lin ^{[1
]}

Zheng, Ji-Min ^{[1
]}

机构：

[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China

来源：

CRYSTAL GROWTH & DESIGN | 2006年 / 6卷 / 11期

关键词：

COORDINATION POLYMERS; ORGANIC FRAMEWORK; TRIMESIC ACID; NETWORKS; CRYSTAL; ARCHITECTURE; COMPLEXES; ZN; SPACER; ANIONS;

D O I：

10.1021/cg0602717

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This paper presents two 2-fold parallel interpenetrated polymers, namely ZnCo(bpp)(m-BDC)(2) (1) and Co(bpp)(p-BDC)(2), based on isomerous 1,3-benzenedicarboxylate (m-BDC) and 1,4-benzenedicarboxylate (p-BDC). Compounds 1 and 2 have been hydrothermally synthesized and characterized by single-crystal X-ray diffraction, IR, ICP, TGA, DSC, and element analysis. 1 crystallizes in the triclinic space group P (1) over bar and affords a three-dimensional (3D) six-connected alpha-Po network, whereas 2 crystallizes in the orthorhombic space group Pbca and gives an usual 2D four-connected 4(4) grid. These interpenetrated topologies should be attributed to the high functionality and adaptability of the 1,3-bis(4-pyridyl) propane (bpp) ligand.

引用

页码：2517 / 2522

页数：6

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