The effects of vitamin C on ZnO crystal formation

被引:36
作者
Cho, Seungho [1 ]
Jeong, Haeyoon [2 ]
Park, Da-Hye [1 ]
Jung, Seung-Ho [1 ]
Kim, Hye-Jin [1 ]
Lee, Kun-Hong [1 ]
机构
[1] Pohang Univ Sci & Technol POSTECH, Dept Chem Engn, Pohang 790784, Gyungbuk, South Korea
[2] Korean Minjok Leadership Acad, Hoengseong Gun 255823, Gangwon, South Korea
来源
CRYSTENGCOMM | 2010年 / 12卷 / 03期
关键词
ZINC-OXIDE NANOWIRES; HYDROTHERMAL GROWTH; ROOM-TEMPERATURE; AQUEOUS-SOLUTION; PHOTOCATALYTIC ACTIVITY; CALCIUM-CARBONATE; CITRIC-ACID; AB-INITIO; NANOSTRUCTURES; MORPHOLOGY;
D O I
10.1039/b916750a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We have studied the effects of L(+)-ascorbic acid (vitamin C) on the formation of ZnO crystals. We carried out a series of experiments under weak acidic to alkaline conditions. We obtained ZnO structures with various distinct morphologies by varying the concentration of vitamin C dissolved in the weak acidic and alkaline solutions. Under weak acidic conditions, if the concentration of added vitamin C exceeds 0.5 mM, mixed amorphous/crystalline vitamin C-ZnO (VitC-ZnO) nanostructures are obtained. We also found that the ZnO content of the VitC-ZnO nanostructures can be controlled by adjusting the concentration of vitamin C added to the reaction solution. On the basis of our results, we propose a mechanism for the formation of the various ZnO structures and VitC-ZnO nanostructures in the presence of vitamin C.
引用
收藏
页码:968 / 976
页数:9
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