Excitation Energy Transfer in Organic Materials: From Fundamentals to Optoelectronic Devices

被引:177
作者
Laquai, Frederic [1 ]
Park, Young-Seo [2 ]
Kim, Jang-Joo [2 ]
Basche, Thomas [3 ]
机构
[1] Max Planck Inst Polymer Res, Max Planck Res Grp Organ Optoelect, D-55124 Mainz, Germany
[2] Seoul Natl Univ, Dept Mat Sci & Engn, OLED Ctr, Seoul 151744, South Korea
[3] Johannes Gutenberg Univ Mainz, Inst Phys Chem, Mainz, Germany
关键词
conjugated polymers; electronic energy transfer; light-emitting diodes (LED); organic electronics; photophysics; single molecule spectroscopy (SMS); LIGHT-EMITTING-DEVICES; TRIPLET-TRIPLET ANNIHILATION; SINGLE-MOLECULE SPECTROSCOPY; TRANSFER EXCITED-STATES; CHARGE-TRANSFER STATE; POWER UP-CONVERSION; HIGH-EFFICIENCY; CONJUGATED POLYMER; MEH-PPV; ELECTROLUMINESCENT DEVICES;
D O I
10.1002/marc.200900309
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In this review, we discuss investigations of electronic excitation energy transfer in conjugated organic materials at the bulk and single molecule level and applications of energy transfer in fluorescent and phosphorescent organic light emitting devices. A brief overview of common descriptions of energy transfer mechanisms is given followed by a discussion of some basic photophysics of conjugated materials including the generation of excited states and their subsequent decay through various channels. In particular, various examples of bimolecular excited state annihilation processes are presented. Energy transfer studies at the single molecule level provide a new tool to study electronic couplings in simple donor/acceptor dyads and conjugated polymers. Finally, energy transfer in organic electronic devices is discussed with particular emphasis on triplet emitter doped OLEDs and blends for white light emission.
引用
收藏
页码:1203 / 1231
页数:29
相关论文
共 251 条
[71]   Nanometer resolution and coherent optical dipole coupling of two individual molecules [J].
Hettich, C ;
Schmitt, C ;
Zitzmann, J ;
Kühn, S ;
Gerhardt, I ;
Sandoghdar, V .
SCIENCE, 2002, 298 (5592) :385-389
[72]   CONFORMATIONAL EFFECTS IN POLY(P-PHENYLENE VINYLENE)S REVEALED BY LOW-TEMPERATURE SITE-SELECTIVE FLUORESCENCE [J].
HEUN, S ;
MAHRT, RF ;
GREINER, A ;
LEMMER, U ;
BASSLER, H ;
HALLIDAY, DA ;
BRADLEY, DDC ;
BURN, PL ;
HOLMES, AB .
JOURNAL OF PHYSICS-CONDENSED MATTER, 1993, 5 (02) :247-260
[73]   Picosecond excitation energy relaxation processes in a ladder-type π-conjugated polymer [J].
Hildner, Richard ;
Lemmer, Ulrich ;
Scherf, Ullrich ;
Koehler, Juergen .
CHEMICAL PHYSICS LETTERS, 2006, 429 (1-3) :103-108
[74]   The Complex Excited-state Behavior of a Polyspirobifluorene Derivative: The Role of Spiroconjugation and Mixed Charge Transfer Character on Excited-state Stabilization and Radiative Lifetime [J].
Hintschich, Susanne I. ;
Rothe, Carsten ;
King, Simon M. ;
Clark, Stewart J. ;
Monkman, Andrew P. .
JOURNAL OF PHYSICAL CHEMISTRY B, 2008, 112 (51) :16300-16306
[75]   Time-resolved measurements of intramolecular energy transfer in single donor/acceptor dyads [J].
Hinze, G ;
Haase, M ;
Nolde, F ;
Müllen, K ;
Basché, T .
JOURNAL OF PHYSICAL CHEMISTRY A, 2005, 109 (30) :6725-6729
[76]   Intramolecular electronic excitation energy transfer in donor/acceptor dyads studied by time and frequency resolved single molecule spectroscopy [J].
Hinze, G. ;
Metivier, R. ;
Nolde, F. ;
Muellen, K. ;
Basche, Th. .
JOURNAL OF CHEMICAL PHYSICS, 2008, 128 (12)
[77]   Controlled non-classical photon emission from single conjugated polymer molecules [J].
Hollars, CW ;
Lane, SM ;
Huser, T .
CHEMICAL PHYSICS LETTERS, 2003, 370 (3-4) :393-398
[78]   Studying and switching electron transfer: From the ensemble to the single molecule [J].
Holman, MW ;
Liu, RC ;
Zang, L ;
Yan, P ;
DiBenedetto, SA ;
Bowers, RD ;
Adams, DM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (49) :16126-16133
[79]   Blue organic electrophosphorescence using exothermic host-guest energy transfer [J].
Holmes, RJ ;
Forrest, SR ;
Tung, YJ ;
Kwong, RC ;
Brown, JJ ;
Garon, S ;
Thompson, ME .
APPLIED PHYSICS LETTERS, 2003, 82 (15) :2422-2424
[80]   Single-molecule spectroscopy of the conjugated polymer MEH-PPV [J].
Hu, DH ;
Yu, J ;
Barbara, PF .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (29) :6936-6937