Oxidation of alkenes by oxodiperoxomolybdenum: Trialkyl(aryl)phosphine oxide complexes

被引：10

作者：

Kiraz, Christine I. Altinis ^{[1
]}

Mora, Luis ^{[1
]}

Jimenez, Leslie S. ^{[1
]}

机构：

[1] Rutgers State Univ, Dept Chem & Biol Chem, Piscataway, NJ 08854 USA

来源：

SYNTHESIS-STUTTGART | 2007年 / 01期

关键词：

epoxidations; organometallic reagents; heterogenous catalysis; molybdenum complexes; green chemistry;

D O I：

10.1055/s-2006-958933

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Catalytic amounts of short-chain (2-4 carbons) trialkylphosphine oxide ligands and MoO5 have been shown to efficiently convert di- and higher substituted alkenes to the corresponding epoxides using a biphasic system with either 30% hydrogen peroxide or 70% TBHP acting as the stoichiometric oxidant.

引用

页码：92 / 96

页数：5

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