Heavier alkaline earth amides as catalysts for the Tischenko reaction

被引：92

作者：

Crimmin, Mark R.

Barrett, Anthony G. M.

Hill, Michael S.

Procopiou, Panayiotis A.

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England

[2] GlaxoSmithKline, Med Res Ctr, Stevenage SG1 2NY, Herts, England

来源：

ORGANIC LETTERS | 2007年 / 9卷 / 02期

关键词：

D O I：

10.1021/ol0627247

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Homoleptic heavier alkaline earth amides, M{N(SiMe3)(2)}(2)(THF)(2) (M = Ca, Sr, and Ba) are reported as precatalysts for the dimerization of aldehydes to the analogous carboxylic esters (Tischenko reaction).

引用

页码：331 / 333

页数：3

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