Magnetic and neutron diffraction study on iridium(IV) perovskites Sr2LnIrO6 (Ln = Ce, Tb)

被引:18
作者
Harada, D [1 ]
Wakeshima, M
Hinatsu, Y
Ohoyama, K
Yamaguchi, Y
机构
[1] Hokkaido Univ, Grad Sch Sci, Div Chem, Sapporo, Hokkaido 0600810, Japan
[2] Tohoku Univ, Mat Res Inst, Sendai, Miyagi 9808577, Japan
关键词
D O I
10.1088/0953-8984/12/14/302
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Powder neutron diffraction measurements have been performed for two tetravalent iridium perovskites, Sr2CeIrO6 (T-N = 21 K) and Sr2TbIrO6 (T-N = 51 K). It is found that moments of Tb4+ in these ordered perovskites are stacked antiferromagnetically along the c-axis, and the magnetic structure is of type I. The ordered magnetic moment of Tb4+ is 4.96 mu(B) at 28 K and 6.60 mu(B) at 2 K. From magnetic susceptibility measurements on Sr2CexTb1-xIrO6, the antiferromagnetic transition temperatures decrease greatly with decreasing Tb4+ ion, which indicates that the pathway of such interactions must involve the Tb4+ ions.
引用
收藏
页码:3229 / 3239
页数:11
相关论文
共 9 条
[1]   THE CRYSTAL AND MAGNETIC-STRUCTURES OF CA2NDRUO6, CA2HORUO6, AND SR2ERRUO6 [J].
BATTLE, PD ;
JONES, CW ;
STUDER, F .
JOURNAL OF SOLID STATE CHEMISTRY, 1991, 90 (02) :302-312
[2]   THE CRYSTAL-STRUCTURES AND MAGNETIC-PROPERTIES OF BA2LARUO6 AND CA2LARUO6 [J].
BATTLE, PD ;
GOODENOUGH, JB ;
PRICE, R .
JOURNAL OF SOLID STATE CHEMISTRY, 1983, 46 (02) :234-244
[3]   THE CRYSTAL AND MAGNETIC-STRUCTURES OF SR2YRUO6 [J].
BATTLE, PD ;
MACKLIN, WJ .
JOURNAL OF SOLID STATE CHEMISTRY, 1984, 52 (02) :138-145
[4]   The crystal and magnetic structures of Ca2YRuO6 and the electronic properties of the series M2+2X3+Ru5+O6 (M = Ca, Sr, Ba; X = La, Y) [J].
BATTLE, PD ;
MACKLIN, WJ .
JOURNAL OF SOLID STATE CHEMISTRY, 1984, 54 (02) :245-250
[5]   THE STRUCTURE AND MAGNETIC-PROPERTIES OF LA(2)MIRO(6) WITH M=MG, CO, NI, AND ZN [J].
CURRIE, RC ;
VENTE, JF ;
FRIKKEE, E ;
IJDO, DJW .
JOURNAL OF SOLID STATE CHEMISTRY, 1995, 116 (01) :199-204
[6]   The structure and magnetic properties of new iridium(IV) perovskites Sr2LnIrO6 (Ln = Ce, Tb) [J].
Harada, D ;
Wakeshima, M ;
Hinatsu, Y .
JOURNAL OF SOLID STATE CHEMISTRY, 1999, 145 (01) :356-360
[7]  
IZUMI F, 1993, RIETVELD METHOD, pCH13
[8]   The new neutron powder diffractometer with a multi-detector system for high-efficiency and high-resolution measurements [J].
Ohoyama, K ;
Kanouchi, T ;
Nemoto, K ;
Ohashi, M ;
Kajitani, T ;
Yamaguchi, Y .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1998, 37 (6A) :3319-3326
[9]   Crystal structures and magnetic properties of ordered perovskites A2R3+Ir5+O6 (A=Sr, Ba; R=Sc, Y, La, Lu) [J].
Wakeshima, M ;
Harada, D ;
Hinatsu, Y .
JOURNAL OF ALLOYS AND COMPOUNDS, 1999, 287 (1-2) :130-136