Multiferroic Behavior Associated with an Order-Disorder Hydrogen Bonding Transition in Metal-Organic Frameworks (MOFs) with the Perovskite ABX3 Architecture

被引：739

作者：

Jain, Prashant ^{[1
,2
,3
]}

Ramachandran, Vasanth ^{[2
]}

Clark, Ronald J. ^{[2
]}

Zhou, Hai Dong ^{[3
]}

Toby, Brian H. ^{[4
]}

Dalal, Naresh S. ^{[2
,3
]}

Kroto, Harold W. ^{[2
]}

Cheetham, Anthony K. ^{[1
]}

机构：

[1] Univ Cambridge, Dept Mat Sci & Met, Cambridge CB2 3QZ, England

[2] Florida State Univ, Dept Chem & Biochem, Tallahassee, FL 32306 USA

[3] Natl High Magnet Field Lab, Tallahassee, FL 32310 USA

[4] Argonne Natl Lab, Adv Photon Source, Argonne, IL 60439 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 38期

基金：

欧洲研究理事会; 美国国家科学基金会;

关键词：

WEAK FERROMAGNETISM; PHASE-TRANSITION; CRYSTAL; SOLIDS; KH2PO4;

D O I：

10.1021/ja904156s

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Multiferroic behavior in perovskite-related metal-organic frameworks of general formula [(CH3)(2)NH2]M(HCOO)(3), where M = Mn, Fe, Co, and Ni, is reported. All four compounds exhibit paraelectric-antiferroelectric phase transition behavior in the temperature range 160-185 K (Mn: 185 K, Fe: 160 K; Co: 165 K; Ni: 180 K); this is associated with an order-disorder transition involving the hydrogen bonded dimethylammonium cations. On further cooling, the compounds become canted weak ferromagnets below 40 K. This research opens up a new class of multiferroics in which the electrical ordering is achieved by means of hydrogen bonding.

引用

页码：13625 / +

页数：5

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