Generation of acylnitroso dienophiles: A study of metal catalysis

被引：36

作者：

Adamo, Mauro F. A. ^{[1
]}

Bruschi, Simone ^{[1
]}

机构：

[1] Royal Coll Surgeons Ireland, Dept Pharmaceut & Med Chem, CSCB, Dublin 2, Ireland

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2007年 / 72卷 / 07期

关键词：

D O I：

10.1021/jo062334y

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHIC] Four novel metal/amine catalysts efficiently converted Boc-NHOH to its acylnitroso species at 5 mol % catalyst loading. These reactions allowed the preparation of polyfunctional hetero Diels-Alder adducts in high yield and from truly commercially available materials.

引用

页码：2666 / 2669

页数：4

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