n-hexane cracking on binderless zeolite HZSM-5 coated monolithic reactors

被引：18

作者：

Antia, JE ^{[1
]}

Israni, K ^{[1
]}

Govind, R ^{[1
]}

机构：

[1] UNIV CINCINNATI,DEPT CHEM ENGN,CINCINNATI,OH 45221

来源：

APPLIED CATALYSIS A-GENERAL | 1997年 / 159卷 / 1-2期

关键词：

configurational diffusion; monolithic reactor; binderless zeolite coating; HZSM-5; hexane cracking;

D O I：

10.1016/S0926-860X(97)00010-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The transformation of n-hexane to gasoline-range hydrocarbons over binderless zeolite HZSM-5 coated monolithic reactors is studied here. Experimental conversion and hydrocarbon product selectivity in these reactors are compared with results reported for conventional packed bed reactors consisting of catalyst pellets, A theoretical analysis reveals that the conversion of n-hexane in HZSM-5 coated monoliths is controlled by configurational counterdiffusion of reactant and product molecules in the intracrystalline zeolite catalyst pores. The average zeolite crystal size of 6 mu m, used in this study, is within the range (0.01-20 mu m) reported for configurational diffusion to occur in n-hexane cracking.

引用

页码：89 / 99

页数：11

共 26 条

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