Water confinement effects in black soap films

被引：20

作者：

Berger, C

Desbat, B

Kellay, H

Turlet, JM

Blaudez, D ^{[1
]}

机构：

[1] Univ Bordeaux 1, UMR 5798 CNRS, Ctr Phys Mol Opt & Hertzienne, F-33405 Talence, France

[2] Univ Bordeaux 1, UMR 5803 CNRS, Lab Physicochim Mol, F-33405 Talence, France

来源：

LANGMUIR | 2003年 / 19卷 / 01期

关键词：

D O I：

10.1021/la020667u

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Water confined in the ultrathin interstitial core of black soap films has been studied by infrared and Raman spectroscopies. Lowering the water core thickness below 1 nm induces spectral modifications in the multicomponent O-H stretching band which can be associated with environment changes for water molecules. Differences observed between nonionic and ionic surfactants allow us to distinguish the sole effect of confinement from the combined effects of confinement and ionic strength. Both trends correlate with previous experimental observations done on different surfactant solutions and with results from numerical simulations.

引用

页码：1 / 5

页数：5

共 31 条

[21] INFRARED AND RAMAN-SPECTRA OF HYDROGEN-BONDED LIQUIDS - EFFECT OF ELECTRICAL ANHARMONICITY ON PROFILES OF HYDROGEN-STRETCHING BANDS [J].