Macromolecular architectures by living and controlled/living polymerizations

被引：567

作者：

Hadjichristidis, Nikos ^{[1
]}

Iatrou, Hermis

Pitsikalis, Marmos

Mays, Jimmy

机构：

[1] Univ Athens, Dept Chem, GR-15771 Athens, Greece

[2] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA

[3] Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA

来源：

PROGRESS IN POLYMER SCIENCE | 2006年 / 31卷 / 12期

关键词：

macromolecular architecture; living polymerization; controlled polymerization;

D O I：

10.1016/j.progpolymsci.2006.07.002

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The discovery of living anionic polymerization by Szwarc 50 years ago opened the way to the synthesis of model polymers. This ground-breaking discovery inspired many researchers to develop controlled/living routes for a plethora of monomers including those not compatible with anionic polymerization. These methods and their combinations serve as an arsenal for the synthesis of well-defined polymeric materials with predetermined properties and a rich variety of applications. A few representative examples of living and controlled/living methodologies for the synthesis of polymers with different macromolecular architectures are presented in this review. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：1068 / 1132

页数：65

共 250 条

[1] Graft copolymers from star-shaped and hyperbranched polystyrene macromonomers [J].