Use of electrospray ionization mass spectrometry to characterize chiral reactive intermediates in a titanium alkoxide mediated sulfoxidation reaction

被引：41

作者：

Bonchio, M

Licini, G

Modena, G

Moro, S

Bortolini, O

Traldi, P

Nugent, WA

机构：

[1] UNIV PADUA,DIPARTIMENTO CHIM ORGAN,CNR,CMRO,I-35131 PADUA,ITALY

[2] UNIV FERRARA,DIPARTMENTO CHIM,I-44100 FERRARA,ITALY

[3] CNR,CSSRCC,I-35131 PADUA,ITALY

[4] DUPONT CO INC,CENT RES & DEV,WILMINGTON,DE 19880

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 09期

关键词：

D O I：

10.1039/a701227f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The ESIMS technique, combined with H-1 NMR evidence, provides a precise inventory of the catalytic Ti-IV precursors and the characterization of the reactive peroxometal complex involved in enantioselective sulfoxidation employing the Ti-IV-homochiral trialkanolamine-alkylhydroperoxide system.

引用

收藏

页码：869 / 870

页数：2

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