Nanowire-quantum-dot solar cells and the influence of nanowire length on the charge collection efficiency

被引:77
作者
Leschkies, Kurtis S. [1 ]
Jacobs, Alan G. [1 ]
Norris, David J. [1 ]
Aydil, Eray S. [1 ]
机构
[1] Univ Minnesota, Dept Chem Engn & Mat Sci, Minneapolis, MN 55455 USA
关键词
SEMICONDUCTOR NANOCRYSTALS; PHOTOVOLTAIC DEVICES; ZNO NANOWIRES; ARRAYS; SILICON; FILMS; TRANSPORT; CDSE;
D O I
10.1063/1.3258490
中图分类号
O59 [应用物理学];
学科分类号
摘要
External quantum efficiency in solar cells based oil junctions between PbSe quantum dots (QDs) and thin ZnO films is increased by replacing the ZnO films with a vertically oriented array of single-crystalline ZnO nanowires, and infiltrating this array with colloidal QDs. When illuminated with 100 mW/cm(2) of simulated solar light. QD-nanowire solar cells exhibited power conversion efficiencies approaching 2%, approximately three times higher than that achieved with thin-film ZnO devices constructed with the same amount of QDs. Significant photocurrent and power conversion improvement with increasing nanowire length is consistent with higher exciton and charge collection efficiencies. (C) 2009 American Institute of Physics [doi:10.1063/1.3258490]
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页数:3
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