Chromium(0)-rhodium(I) metal exchange:: Synthesis and X-ray structure of new Fischer (NHC)carbene complexes of rhodium(I)

被引：31

作者：

Barluenga, Jose ^{[1
]}

Vicente, Ruben ^{[1
]}

Lopez, Luis A. ^{[1
]}

Tomas, Miguel ^{[1
]}

机构：

[1] Univ Oviedo, Inst Quim Organomet Enrique Moles, CSIC, Unidad Asociada, E-33006 Oviedo, Spain

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2006年 / 691卷 / 26期

关键词：

rhodium; NHC-complexes; Fischer carbene complexes; carbene transfer;

D O I：

10.1016/j.jorganchem.2006.09.013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An easy approach to Fischer (NHC)carbene complexes of rhodium(1) 3 from methoxy- and aminocarbene complexes of chromium 1 and (NHC)(cod)RhCl (2) is described. The process involves the transfer of the carbene unit and a CO ligand from chromium to rhodium. The X-ray analysis is provided for 3d and the preliminary results on their thermal stability and reactivity toward alkynes and allenes are also reported. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：5642 / 5647

页数：6

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