The dynamics of thin polymer films

被引：86

作者：

Jones, RAL ^{[1
]}

机构：

[1] Univ Sheffield, Dept Phys & Astron, Sheffield S3 7RH, S Yorkshire, England

来源：

CURRENT OPINION IN COLLOID & INTERFACE SCIENCE | 1999年 / 4卷 / 02期

关键词：

D O I：

10.1016/S1359-0294(99)00025-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An increasing amount of experimental data now supports the idea that the dynamics of thin polymer films is different from bulk. An experimental consensus now supports the previously controversial view that glass transition temperatures of thin polymer films on weakly interacting substrates are reduced from bulk values, but evidence for whether the surface has a higher mobility than the bulk is still contradictory.

引用

页码：153 / 158

页数：6

共 51 条

[1] Dynamics of glassy polymer melts in confined geometry: A Monte Carlo simulation [J].

Baschnagel, J ;

Binder, K .

JOURNAL DE PHYSIQUE I, 1996, 6 (10) :1271-1294

[2] ON THE INFLUENCE OF HARD WALLS ON STRUCTURAL-PROPERTIES IN POLYMER GLASS SIMULATION [J].

BASCHNAGEL, J ;

BINDER, K .

MACROMOLECULES, 1995, 28 (20) :6808-6818

[3] Simulation of the glass transition in polymeric systems: evidence for an underlying phase transition? [J].

Binder, K ;

Baschnagel, J ;

Bohmer, S ;

Paul, W .

PHILOSOPHICAL MAGAZINE B-PHYSICS OF CONDENSED MATTER STATISTICAL MECHANICS ELECTRONIC OPTICAL AND MAGNETIC PROPERTIES, 1998, 77 (02) :591-608

[4] Direct imaging single molecule diffusion in a solid polymer host [J].

Bopp, MA ;

Meixner, AJ ;

Tarrach, G ;

ZschokkeGranacher, I ;

Novotny, L .

CHEMICAL PHYSICS LETTERS, 1996, 263 (06) :721-726

[5] Super-resolution fluorescence imaging of single dye molecules in thin polymer films [J].

Bopp, MA ;

Tarrach, G ;

Lieb, MA ;

Meixner, AJ .

JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A, 1997, 15 (03) :1423-1426

[6] Interface and surface effects on the glass transition in thin polystyrene films [J].

DeMaggio, GB ;

Frieze, WE ;

Gidley, DW ;

Zhu, M ;

Hristov, HA ;

Yee, AF .

PHYSICAL REVIEW LETTERS, 1997, 78 (08) :1524-1527

[7]

Doi M., 1986, The theory of polymer dynamics

[8] Effect of hard polymer filler particles on polymer diffusion in a low-Tg latex film [J].

Feng, JR ;

Odrobina, E ;

Winnik, MA .

MACROMOLECULES, 1998, 31 (16) :5290-5299

[9] Effect of free surfaces on the glass transition temperature of thin polymer films [J].

Forrest, JA ;

DalnokiVeress, K ;

Stevens, JR ;

Dutcher, JR .

PHYSICAL REVIEW LETTERS, 1996, 77 (10) :2002-2005

[10] Relaxation dynamics in ultrathin polymer films [J].

Forrest, JA ;

Svanberg, C ;

Revesz, K ;

Rodahl, M ;

Torell, LM ;

Kasemo, B .

PHYSICAL REVIEW E, 1998, 58 (02) :R1226-R1229

← 1 2 3 4 5 6 →