Endohedral stannaspherenes M@Sn12-:: A rich class of stable molecular cage clusters

被引：104

作者：

Cui, Li-Feng

Huang, Xin

Wang, Lei-Ming

Li, Jun

Wang, Lai-Sheng

机构：

[1] Pacific NW Natl Lab, WR Wiley Environm Mol Sci Lab, Richland, WA 99352 USA

[2] Washington State Univ, Dept Phys, Richland, WA 99354 USA

[3] Pacific NW Natl Lab, Div Chem Sci, Richland, WA 99352 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 05期

关键词：

D O I：

10.1002/anie.200603226

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Trapped in a cage: Combined experimental and theoretical evidence shows that the stannaspherene Sn122- can trap a transition-metal or f-element atom (green) to form a stable endohedral cluster (see figure). The central metal atom induces very little distortion in the icosahedral cage. The clusters can be viewed as "superatoms" for use in materials with tunable magnetic, electronic, and chemical properties. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：742 / 745

页数：4

共 48 条

[31] LI X, 2002, ANGEW CHEM, V114, P4980
[32] THE ELECTRONIC STRUCTURE OF AN ICOSAHEDRON OF BORON ATOMS
LONGUETHIGGINS, HC
ROBERTS, MD
[J]. PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1955, 230 (1180): : 110 - 119
[33] Extremely stable metal-encapsulated AlPb10+ and AlPb12+ clusters:: Mass-spectrometric discovery and density functional theory study -: art. no. 163401
Neukermans, S
Janssens, E
Chen, ZF
Silverans, RE
Schleyer, PV
Lievens, P
[J]. PHYSICAL REVIEW LETTERS, 2004, 92 (16) : 163401 - 1
[34] *PAC NW NAT LAB, NWCHEM COMP CHEM PAC
[35] PERDEW JP, 1992, PHYS REV B, V45, P13, DOI DOI 10.1103/PHYSREVB.45.13244)
[36] THE ISOLATION OF THE ICOSAHEDRAL B12H12-2 ION
PITOCHELLI, AR
HAWTHORNE, MF
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1960, 82 (12) : 3228 - 3229
[37] AN AB-INITIO INVESTIGATION OF THE MOLECULES X(2), CUX, CU(2)X AND CUX(2) (X=SI,GE, AND SN)
PLASS, W
STOLL, H
PREUSS, H
SAVIN, A
[J]. JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 1995, 339 : 67 - 81
[38] Pyykkö P, 2002, ANGEW CHEM INT EDIT, V41, P2174, DOI 10.1002/1521-3773(20020617)41:12<2174::AID-ANIE2174>3.0.CO
[39] 2-8
[40] Pyykko P., 2002, ANGEW CHEM, V114, P2278, DOI DOI 10.1002/1521-3757(20020617)114:12<

← 1 2 3 4 5 →