Synthesis, structure, and properties of PBO/SWNT composites

被引:418
作者
Kumar, S [1 ]
Dang, TD
Arnold, FE
Bhattacharyya, AR
Min, BG
Zhang, XF
Vaia, RA
Park, C
Adams, WW
Hauge, RH
Smalley, RE
Ramesh, S
Willis, PA
机构
[1] Georgia Inst Technol, Sch Text & Fiber Engn, Atlanta, GA 30332 USA
[2] Air Force Res Lab, Wright Patterson AFB, OH 45433 USA
[3] NASA, Langley Res Ctr, ICASE, Hampton, VA 23681 USA
[4] Rice Univ, Ctr Nanoscale Sci & Technol, Houston, TX 77005 USA
关键词
D O I
10.1021/ma0205055
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Poly(p-phenylene benzobisoxazole) (PBO) has been synthesized in the presence of single-wall carbon nanotubes (SWNTs) in poly(phosphoric acid) (PPA) using typical PBO polymerization conditions. PBO and PBO/SWNT lyotropic liquid crystalline solutions in PPA have been spun into fibers using dry-jet wet spinning. The tensile strength of the PBO/SWNT fiber containing 10 wt % SWNTs is about 50% higher than that of the control PBO fibers containing no SWNTs. The structure and morphology of these fibers have been studied.
引用
收藏
页码:9039 / 9043
页数:5
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