Stereoselective stilbene epoxidation over supported gold-based catalysts

被引：70

作者：

Lignier, Pascal ^{[1
]}

Morfin, Franck ^{[1
]}

Mangematin, Stephane ^{[1
]}

Massin, Laurence ^{[1
]}

Rousset, Jean-Luc ^{[1
]}

Caps, Valerie ^{[1
]}

机构：

[1] Inst Rech Catalyse, CNRS, F-69626 Villeurbanne, France

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 02期

关键词：

D O I：

10.1039/b610546g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The gold reference catalyst Au/TiO2 exhibits high activity in the stereoselective epoxidation of trans-stilbene in methylcyclohexane in the presence of 5 mol% TBHP, by taking part in a chain reaction involving the activation of molecular oxygen by a radical produced from methylcyclohexane.

引用

页码：186 / 188

页数：3

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