Construction of a new open-framework solid from 1,3,5-cyclohexanetricarboxylate and zinc(II) building blocks

被引:61
作者
Yaghi, OM
Jernigan, R
Li, HL
Davis, CE
Groy, TL
机构
[1] Department of Chemistry and Biochemistry, Arizona State University, Tempe
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1997年 / 14期
关键词
D O I
10.1039/a702287e
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Addition copolymerization of cis,cis-1,3,5-cyclohexanetricarboxylate (CTC) with zinc(II) at 25 degrees C yielded the extended co-ordination solid, Zn-3[(CTC)(C5H5N)](2) . 2(CH3)(2)NC(O)H, which has one-dimensional channels with an aperture of nearly 6 Angstrom as found by an X-ray crystallographic study.
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页码:2383 / 2384
页数:2
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