Amidine-mediated delivery of CO2 from gas phase to reaction system for highly efficient synthesis of cyclic carbonates from epoxides

被引：79

作者：

Barkakaty, Balaka ^{[1
]}

Morino, Kazuhide ^{[1
]}

Sudo, Atsushi ^{[1
]}

Endo, Takeshi ^{[1
]}

机构：

[1] Kinki Univ, Mol Engn Inst, Fukuoka 8208555, Japan

来源：

GREEN CHEMISTRY | 2010年 / 12卷 / 01期

关键词：

CHEMICAL FIXATION; COUPLING REACTION; IONIC LIQUID; PROPYLENE CARBONATE; TERMINAL EPOXIDES; ROOM-TEMPERATURE; CATALYTIC AMOUNT; BASE CATALYSTS; DIOXIDE; COMPLEX;

D O I：

10.1039/b916235f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel, efficient synthesis of cyclic carbonates from the reaction of epoxides and gaseous CO2 under mild conditions (1 atm, rt to 45 degrees C) was achieved in reasonable yields (65-83%) by using N-methyltetrahydropyrimidine (MTHP) that facilitated efficient delivery of CO2 from the gas phase to the reaction system.

引用

收藏

页码：42 / 44

页数：3

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