2,8-Dimethyl-1,9-dinitro-6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine

被引:7
作者
Bhuiyan, M. Delower H.
Jensen, Paul
Try, Andrew C.
机构
[1] Macquarie Univ, Dept Chem & Biomol Sci, N Ryde, NSW 2109, Australia
[2] Univ Sydney, Sch Chem, Crystal Struct Anal Facil, Sydney, NSW 2006, Australia
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2007年 / 63卷
关键词
D O I
10.1107/S1600536807002991
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the molecule of the title compound, C17H16N4O4, the 2,8-dimethyl-1,9-dinitro analogue of Troger's base, the diazocine bridge imparts a twist such that the two aryl rings are offset with respect to one another. The dihedral angle between the two benzene rings is 94.75(4)degrees.
引用
收藏
页码:O908 / O909
页数:2
相关论文
共 10 条
[1]   TABLES OF BOND LENGTHS DETERMINED BY X-RAY AND NEUTRON-DIFFRACTION .1. BOND LENGTHS IN ORGANIC-COMPOUNDS [J].
ALLEN, FH ;
KENNARD, O ;
WATSON, DG ;
BRAMMER, L ;
ORPEN, AG ;
TAYLOR, R .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1987, (12) :S1-S19
[2]  
*BRUK AN XRAY INST, 1998, SMART VERS 5 054
[3]  
*BRUK AXS INC, 2003, SAINT VERS 6 45 SHEL
[4]   GENERAL DEFINITION OF RING PUCKERING COORDINATES [J].
CREMER, D ;
POPLE, JA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (06) :1354-1358
[5]   2,4,8,10-tetrabromo-6H,12H-5,11-methano-dibenzo[b,f][1,5]diazocine [J].
Faroughi, Masoud ;
Try, Andrew C. ;
Turner, Peter .
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 :O3893-O3894
[6]  
GUZEI IA, 2005, MODICIFER VERS DEC 1
[7]   A convenient synthesis of 4-aminoaryl substituted cyclic imides [J].
Mederski, WWKR ;
Baumgarth, M ;
Germann, M ;
Kux, D ;
Weitzel, T .
TETRAHEDRON LETTERS, 2003, 44 (10) :2133-2136
[8]  
Sheldrick G. M., 1997, SHELXS 97 PROGRAM CR, P38
[9]  
Sheldrick G.M., 1996, SADABS VERSION 2008
[10]   Introduction of aromatic and heteroaromatic groups in the 2-and 8-positions of the Troger's base core by Suzuki, Stille and Negishi cross-coupling reactions -: A comparative study [J].
Solano, C ;
Svensson, D ;
Olomi, Z ;
Jensen, J ;
Wendt, OF ;
Wärnmark, K .
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2005, 2005 (16) :3510-3517