Old Molecules, New Concepts: [Ru(bpy)3]2+ as a Molecular Encoder-Decoder

被引：113

作者：

Ceroni, Paola ^{[1
]}

Bergamini, Giacomo ^{[1
]}

Balzani, Vincenzo ^{[1
]}

机构：

[1] Univ Bologna, Dept Chem G Ciamician, I-40126 Bologna, Italy

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 45期

关键词：

electrochemistry; luminescence; molecular devices; photochemistry; ruthenium; KEYPAD LOCK; LOGIC; PHOTOCHEMISTRY; PHOTOPHYSICS; SYSTEMS; ELECTROCHEMISTRY; COMPLEXES; RUTHENIUM; SWITCHES; ELEMENTS;

D O I：

10.1002/anie.200904764

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Totally logical: The well-known complex [Ru(bpy)3]2+ (bpy = 2,2'-bipyridine) can perform as both a 4-to-2 encoder and a 2to-4 decoder (see picture; gray C, blue N, red Ru) by a combination of electronic and photonic inputs and outputs. The system can be reset in situ without the addition of chemical reagents. This approach is considered as an alternative route to solidstate molecular electronics and the design and construction of chemical computers. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8516 / 8518

页数：3

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