Steam and auto-thermal reforming of bio-ethanol over MgO and CeO2Ni supported catalysts

被引：170

作者：

Frusteri, F.

Freni, S.

Chiodo, V.

Donato, S.

Bonura, G.

Cavallaro, S.

机构：

[1] Ist CNR, TAE, I-98126 Messina, Italy

[2] Univ Messina, Dipartimento Chim Ind & Ingn Mat, I-98166 Messina, Italy

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2006年 / 31卷 / 15期

关键词：

hydrogen; bio-ethanol; steam reforming; MCFC; Ni catalysts; coke formation;

D O I：

10.1016/j.ijhydene.2006.02.024

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ethanol reforming over MgO and CeO2 Ni supported catalysts in molten carbonate fuel cell (MCFC) simulated operative conditions has been investigated. Results revealed that an Optimum O-2/C ratio (ATR condition) exists to enhance the performance of both catalysts which otherwise significantly deactivate mainly due to the coke formation. Oxygen contributes to depress coke formation but in some cases promotes acetaldehyde formation specially on Ni/CeO2 catalysts. Very high H-2 selectivity (> 98%) in steam reforming (SR) were obtained on both Ni/MgO and Ni/CeO2 catalysts by operating at 650 degrees C while in ATR conditions a decrease in hydrogen selectivity was observed at high GHSV only since reactions involved in the reaction mechanism are not at equilibrium. (c) 2006 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.

引用

页码：2193 / 2199

页数：7

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