The lithium amide induced rearrangement of epoxysulfones derived from bicyclo[2.2.1]heptane system

被引：9

作者：

Arjona, O ^{[1
]}

Menchaca, R ^{[1
]}

Plumet, J ^{[1
]}

机构：

[1] Univ Complutense Madrid, Fac Quim, Dept Quim Organ 1, E-28040 Madrid, Spain

来源：

TETRAHEDRON | 2000年 / 56卷 / 24期

关键词：

bicyclic aliphatic compounds; carbenes and carbenoids; epoxides; lithium amides;

D O I：

10.1016/S0040-4020(00)00294-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Lithium amides induce rearrangement of the title compounds 1 to afford nortricyclanones 4 via a ketocarbene intermediate. Compounds 4 undergo hydride transfer reduction and imino aldol condensation to afford the other observed reaction products. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：3901 / 3907

页数：7

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