A convenient approach to the aminocyclitol fragment of pancratistatin from 7-oxanorbornenes

被引：26

作者：

Acena, JL

Arjona, O

Iradier, F

Plumet, J

机构：

[1] Depto. de Quim. Orgánica I, Facultad de Química, Universidad Complutense

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 01期

关键词：

D O I：

10.1016/0040-4039(95)02084-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A totally stereoselective route to an analogue aminocyclitol fragment of the alkaloid pancratistatin has been achieved starting from a 7-oxanorbornenic disulfone. The key step was the alkylative cleavage of the oxygen bridge to produce a highly oxygenated cyclohexenyl sulfone.

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页码：105 / 106

页数：2

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