Preparation and properties of graphene nanosheets-polystyrene nanocomposites via in situ emulsion polymerization

被引:334
作者
Hu, Huating [1 ]
Wang, Xianbao [1 ,2 ]
Wang, Jingchao [1 ]
Wan, Li [1 ]
Liu, Fangming [1 ]
Zheng, Han [1 ]
Chen, Rong [1 ]
Xu, Chunhui [1 ]
机构
[1] Hubei Univ, Fac Mat Sci & Engn, Wuhan 430062, Peoples R China
[2] Hubei Univ, Minist Educ Key Lab Green Preparat & Applicat Fun, Wuhan 430062, Peoples R China
基金
中国国家自然科学基金;
关键词
SINGLE-LAYER GRAPHENE; GRAPHITE OXIDE; CHEMICAL-REDUCTION; CONDUCTIVITY; FILMS;
D O I
10.1016/j.cplett.2009.11.024
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Graphene nanosheets-polystyrene nanocomposites were prepared by in situ emulsion polymerization and reduction of graphene oxide using hydrazine hydrate. PS microspheres covalently linked to the edges of graphene nanosheets. The polystyrene-absorbed graphene has been dispersed well in the solvents of toluene and chloroform. The nanocomposites display high electrical conductivity, and a considerable increase in glass-transition temperature and good thermal stability of PS are also achieved. The facile and environmental-friendly technique presented here is an effective and promising method of functionalization of graphene sheets by polymers or other compounds. (C) 2009 Elsevier B. V. All rights reserved.
引用
收藏
页码:247 / 253
页数:7
相关论文
共 31 条
[1]   Superior thermal conductivity of single-layer graphene [J].
Balandin, Alexander A. ;
Ghosh, Suchismita ;
Bao, Wenzhong ;
Calizo, Irene ;
Teweldebrhan, Desalegne ;
Miao, Feng ;
Lau, Chun Ning .
NANO LETTERS, 2008, 8 (03) :902-907
[2]   Graphite oxide:: Chemical reduction to graphite and surface modification with primary aliphatic amines and amino acids [J].
Bourlinos, AB ;
Gournis, D ;
Petridis, D ;
Szabó, T ;
Szeri, A ;
Dékány, I .
LANGMUIR, 2003, 19 (15) :6050-6055
[3]   Variable temperature Raman microscopy as a nanometrology tool for graphene layers and graphene-based devices [J].
Calizo, I. ;
Miao, F. ;
Bao, W. ;
Lau, C. N. ;
Balandin, A. A. .
APPLIED PHYSICS LETTERS, 2007, 91 (07)
[4]   The effect of substrates on the Raman spectrum of graphene: Graphene-on-sapphire and graphene-on-glass [J].
Calizo, Irene ;
Bao, Wenzhong ;
Miao, Feng ;
Lau, Chun Ning ;
Balandin, Alexander A. .
APPLIED PHYSICS LETTERS, 2007, 91 (20)
[5]   Noncovalent sidewall functionalization of single-walled carbon nanotubes for protein immobilization [J].
Chen, RJ ;
Zhang, YG ;
Wang, DW ;
Dai, HJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (16) :3838-3839
[6]   Preparation and characterization of graphene oxide paper [J].
Dikin, Dmitriy A. ;
Stankovich, Sasha ;
Zimney, Eric J. ;
Piner, Richard D. ;
Dommett, Geoffrey H. B. ;
Evmenenko, Guennadi ;
Nguyen, SonBinh T. ;
Ruoff, Rodney S. .
NATURE, 2007, 448 (7152) :457-460
[7]   Graphene-based Composite Thin Films for Electronics [J].
Eda, Goki ;
Chhowalla, Manish .
NANO LETTERS, 2009, 9 (02) :814-818
[8]   The rise of graphene [J].
Geim, A. K. ;
Novoselov, K. S. .
NATURE MATERIALS, 2007, 6 (03) :183-191
[9]   Raman scattering from high-frequency phonons in supported n-graphene layer films [J].
Gupta, A. ;
Chen, G. ;
Joshi, P. ;
Tadigadapa, S. ;
Eklund, P. C. .
NANO LETTERS, 2006, 6 (12) :2667-2673
[10]   PREPARATION OF GRAPHITIC OXIDE [J].
HUMMERS, WS ;
OFFEMAN, RE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) :1339-1339