First reductive dimerization of a polycyclic azine

被引：9

作者：

Berthet, Jean-Claude ^{[1
]}

Thuery, Pierre ^{[1
]}

Baudin, Cecile ^{[2
]}

Boizot, Bruno ^{[2
]}

Ephritikhine, Michel ^{[1
]}

机构：

[1] CEA, IRAMIS, SIS2M, CNRS URA 331, F-91191 Gif Sur Yvette, France

[2] Ecole Polytech, CEA, IRAMIS, LSI, F-91128 Palaiseau, France

来源：

DALTON TRANSACTIONS | 2009年 / 37期

关键词：

LANTHANIDE(III)/ACTINIDE(III) DIFFERENTIATION; MAGNETIC-PROPERTIES; COMPLEXES; 2,4,6-TRIS(2-PYRIDYL)-1,3,5-TRIAZINE; LIGANDS; TETRAPHENYLBORATE; COORDINATION; REACTIVITY; OXIDATION; THULIUM;

D O I：

10.1039/b909547k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The tptz molecule is reduced by potassium into its anion-radical in the compound K(tptz)(2) (1), whereas it is reductively coupled by SmI(2) and UI(3)(py)(4) into the bis-triazinide ligand in the dinuclear complexes [Sm(2)(tptz-tptz)(DMF)(8)][I](4)center dot 3.5DMF (2 center dot 3.5DMF) and U(2)I(6)(tptz-tptz)(MeCN)(2)center dot 2MeCN (3 center dot 2MeCN) where each metal ion occupies a pentadentate N(5) cavity of the [tptz-tptz](2-) ligand.

引用

页码：7613 / 7616

页数：4

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