Aluminum complexes supported by tridentate aminophenoxide ligand as efficient catalysts for ring-opening polymerization of ε-caprolactone

被引：110

作者：

Chen, CT ^{[1
]}

Huang, CA ^{[1
]}

Huang, BH ^{[1
]}

机构：

[1] Natl Chung Hsing Univ, Dept Chem, Taichung 402, Taiwan

来源：

MACROMOLECULES | 2004年 / 37卷 / 21期

关键词：

D O I：

10.1021/ma0492014

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Aluminum complexes bearing dianionic amine bis(phenolate) ligand are described. Reactions of ligand precursors H2O2NMe or H2O2NPr [H2O2NMe = (CH3)N-(CH2-2-HO-3.5-C6H2(Bu-t)(2))(2); H2O2NPr = (CH3CH2CH2)N-(CH2-2-HO-3,5-C6H2(Bu-t)(2))2] with 1.1 mol equiv of AlMe3 in toluene afford MeAlO2-NMe) (1) and MeAI(O2NPr) (2) as four-coordinate aluminum methyl complexes. The molecular structures are reported for compounds 1 and 2. Both compounds show excellent catalytic activity toward the ring-opening polymerization of is an element of-caprolactone in the presence of benzyl alcohol.

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页码：7968 / 7973

页数：6

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