[Pd3(InCp)4(μ2-InCp)4]:: Three linearly arranged palladium atoms wrapped into a fluxional shell of eight InCp* ligands

被引：27

作者：

Steinke, T ^{[1
]}

Gemel, C ^{[1
]}

Winter, M ^{[1
]}

Fischer, RA ^{[1
]}

机构：

[1] Ruhr Univ Bochum, Lehrstuhl Anorgan Chem 2, D-44780 Bochum, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2002年 / 41卷 / 24期

关键词：

D O I：

10.1002/anie.200290041

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

There is still much to discover: The assumption that monovalent Group 13 organometallic compounds exhibit a high potential as ligands in organometallic chemistry beyond their analogy to CO is confirmed by the synthesis of the title compound 1. Complex 1, the structure of which is unique and has no analogue in carbonyl cluster chemistry, is prepared by reaction of [(tmeda)Pd(CH3)2] with [InCp*]. tmeda = N,N,N′,N′-tetramethylethylenediamine, Cp* = pentamethyl-cyclopentadienide.

引用

页码：4761 / 4763

页数：3

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[Pd3(InCp*)4(μ2-InCp*)4]:: Three linearly arranged palladium atoms wrapped into a fluxional shell of eight InCp* ligands

[Pd3(InCp)4(μ2-InCp)4]:: Three linearly arranged palladium atoms wrapped into a fluxional shell of eight InCp* ligands