Polymeric Monosaccharide Receptors Responsive at Neutral pH

被引：131

作者：

Kim, Kyoung Taek ^{[1
]}

Cornelissen, Jeroen J. L. M. ^{[1
]}

Nolte, Roeland J. M. ^{[1
]}

van Hest, Jan C. M. ^{[1
]}

机构：

[1] Radboud Univ Nijmegen, Inst Mol & Mat, NL-6525 ED Nijmegen, Netherlands

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 39期

关键词：

BORONIC ACID; BLOCK-COPOLYMERS; BINDING; SENSOR; SITES; WATER; BOND;

D O I：

10.1021/ja905652w

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We present the first detailed report of the synthesis of Wulff-type styrenic monomers and their polymerization by radical addition-fragmentation chain transfer (RAFT) methods. The resulting polymers and block copolymers exhibit sugar-responsive solubilization in aqueous buffer solutions (pH = 7.4-7.8) in the presence of monosaccharides such as D-fructose and D-glucose.

引用

页码：13908 / +

页数：3

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