Two-photon and three-photon absorption in an organometallic dendrimer

被引：114

作者：

Samoc, Marek

Morrall, Joseph P.

Dalton, Gulliver T.

Cifuentes, Marie P.

Humphrey, Mark G. ^{[1
]}

机构：

[1] Australian Natl Univ, Dept Chem, Canberra, ACT 0200, Australia

[2] Australian Natl Univ, Res Sch Phys Sci & Engn, Laser Phys Ctr, Canberra, ACT 0200, Australia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 05期

关键词：

absorption; alkynyl ligands; dendrimers; nonlinear optics; ruthenium;

D O I：

10.1002/anie.200602341

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three at a time: The wavelength dependence of nonlinear absorption and non-linear refraction of a peripherally nitrophenylethynyl-functionalized first-generation arylethynylruthenium dendrimer (see picture; dppe = 1,2-bis(diphenylphosphanyl)ethane) was examined in the range 625-1500 nm by employing fs pulses. The compound is a strong two-photon absorber in the range 600-800 nm and an exceptional three-photon absorber in the range 1100-1200 nm. (Chemical Equation Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

收藏

页码：731 / 733

页数：3

相关论文

共 23 条

[1] Optical limiting in the visible range:: molecular engineering around N4,N4′-bis(4-methoxyphenyl)-N4,N4′-diphenyl-4,4′-diaminobiphenyl [J].

Anémian, R ;

Morel, Y ;

Baldeck, PL ;

Paci, B ;

Kretsch, K ;

Nunzi, JM ;

Andraud, C .

JOURNAL OF MATERIALS CHEMISTRY, 2003, 13 (09) :2157-2163

[2] Cooperative enhancement of two-photon absorption in multi-branched structures [J].

Chung, SJ ;

Kim, KS ;

Lin, TH ;

He, GS ;

Swiatkiewicz, J ;

Prasad, PN .

JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (49) :10741-10745

[3] One-, two- and three-photon spectroscopy of π-conjugated dendrimers:: cooperative enhancement and coherent domains [J].

Drobizhev, M ;

Rebane, A ;

Suo, Z ;

Spangler, CW .

JOURNAL OF LUMINESCENCE, 2005, 111 (04) :291-305

[4] Cooperative enhancement of two- and three-photon absorption in dendrimers and their underlying coherent domain structure [J].

Drobizhev, M ;

Karotki, A ;

Dzenis, Y ;

Kruk, M ;

Rebane, A ;

Suo, Z ;

Spangler, CW .

NONLINEAR OPTICAL TRANSMISSION AND MULTIPHOTON PROCESSES IN ORGANICS, 2003, 5211 :38-47

[5] Uncovering coherent domain structure in a series of π-conjugated dendrimers by simultaneous three-photon absorption [J].

Drobizhev, M ;

Karotki, A ;

Kruk, M ;

Dzenis, Y ;

Rebane, A ;

Suo, Z ;

Spangler, CW .

JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (14) :4221-4226

[6] Dendrimer molecules with record large two-photon absorption cross section [J].

Drobizhev, M ;

Karotki, A ;

Rebane, A ;

Spangler, CW .

OPTICS LETTERS, 2001, 26 (14) :1081-1083

[7] Observation of stimulated emission by direct three-photon excitation [J].

He, GS ;

Markowicz, PP ;

Lin, TC ;

Prasad, PN .

NATURE, 2002, 415 (6873) :767-770

[8]

Lin TC, 2003, ADV POLYM SCI, V161, P157

[9] Measuring serotonin distribution in live cells with three-photon excitation [J].

Maiti, S ;

Shear, JB ;

Williams, RM ;

Zipfel, WR ;

Webb, WW .

SCIENCE, 1997, 275 (5299) :530-532

[10] Organometallic complexes for nonlinear optics. 17. Synthesis, third-order optical nonlinearities and two-photon absorption cross section of an alkynylruthenium dendrimer [J].

McDonagh, AM ;

Humphrey, MG ;

Samoc, M ;

Luther-Davies, B .

ORGANOMETALLICS, 1999, 18 (25) :5195-5197