Chemiluminescence from the reaction of tin(II) with tris(2,2′-bipyridyl)ruthenium(III)

被引:3
作者
Gange, Michelle E. [1 ]
Parratt, Simon C. [2 ]
Jones, Philip [3 ]
Francis, Paul S. [1 ]
Barnett, Neil W. [1 ]
机构
[1] Deakin Univ, Sch Life & Environm Sci, Geelong, Vic 3217, Australia
[2] Kardinia Int Coll, Geelong, Vic 3220, Australia
[3] Univ Plymouth, Dept Environm Sci, Plymouth PLA 8AA, Devon, England
关键词
RUTHENIUM(II) BIPYRIDYL COMPLEX; CROWN-ETHER MOIETY; ELECTROGENERATED CHEMILUMINESCENCE; AQUEOUS-SOLUTION; METAL-IONS; REDUCTION; ELECTROCHEMILUMINESCENCE; SYSTEM; TIN;
D O I
10.1039/b918641g
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Unlike many other metal and metalloid ions, tin(II) elicits intense, analytically useful chemiluminescence upon reaction with tris(2,2'-bipyridyl) ruthenium(III) in acidic aqueous solution. This finding provides new insight into the nature of this widely used reagent and has enabled the first direct, selective determination of a metal ion with tris(2,2'-bipyridyl) ruthenium(III).
引用
收藏
页码:2397 / 2399
页数:3
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