Water Sorption and Dye Uptake Studies of Highly Swollen AAm/AMPS Hydrogels and Semi-IPNs with PEG

被引:37
作者
Karadag, Erdener [1 ]
Kundakci, Semiha [1 ]
Uzum, Omer Baris [1 ]
机构
[1] Adnan Menderes Univ, Dept Chem, Fen Edebiyat Fac, TR-09010 Aydin, Turkey
关键词
2-Acrylamido-2-methyl-1-propanesulfonic acid; Acrylamide; Hydrogel; Interpenetrating polymer networks; Swelling; Toluidine Blue sorption; DRUG-DELIVERY; HEAVY-METALS; RELEASE; BIOMATERIALS; ADSORPTION; PROTEINS; REMOVAL; ACID);
D O I
10.1080/03602550903159044
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 [高分子化学与物理];
摘要
A semi-interpenetrating network (semi-IPNs) hydrogel, composed of acrylamide (AAm) with 2-acrylamido-2-methyl-1-propane-sulfonic acid (AMPS) as co-monomer, with poly(ethylene glycol) (PEG) and two multifunctional cross-linkers such as 1,4-butanediol dimethacrylate (BDMA), and trimethylolpropane triacrylate (TMPTA) was prepared. AAm/AMPS hydrogels and AAm/AMPS/PEG semi-IPNs were synthesized by free radical solution polymerization. Swelling experiments were performed in water at 25 degrees C, gravimetrically. For sorption of Toluidin Blue (Basic Blue 17, TB) into AAm/AMPS hydrogels and AAm/AMPS/PEG semi-IPNs was studied by batch sorption technique at 25 degrees C. Dye removal capacity, removal effiency and partition coefficient of the hydrogels was investigated.
引用
收藏
页码:1217 / 1229
页数:13
相关论文
共 37 条
[1]
Synthesis and characterization of PVP/AAc copolymer hydrogel and its applications in the removal of heavy metals from aqueous solution [J].
Ali, AEH ;
Shawky, HA ;
Abd el Rehim, HA ;
Hegazy, EA .
EUROPEAN POLYMER JOURNAL, 2003, 39 (12) :2337-2344
[2]
Polysiloxanes in macromolecular architecture [J].
Bischoff, R ;
Cray, SE .
PROGRESS IN POLYMER SCIENCE, 1999, 24 (02) :185-219
[3]
Thermosensitive poly(N-isopropylacrylamide-co-acrylamide) hydrogels:: Synthesis, swelling and interaction with ionic surfactants [J].
Caykara, T ;
Kiper, S ;
Demirel, G .
EUROPEAN POLYMER JOURNAL, 2006, 42 (02) :348-355
[4]
Recent developments in polysaccharide-based materials used as adsorbents in wastewater treatment [J].
Crini, G .
PROGRESS IN POLYMER SCIENCE, 2005, 30 (01) :38-70
[5]
Dengre R, 2000, J APPL POLYM SCI, V76, P1706, DOI 10.1002/(SICI)1097-4628(20000613)76:11<1706::AID-APP12>3.0.CO
[6]
2-W
[7]
Acrylamide/2-acrylamido-2-methylpropane sulfonic acid sodium salt-based hydrogels: synthesis and characterization [J].
Durmaz, S ;
Okay, O .
POLYMER, 2000, 41 (10) :3693-3704
[8]
Ende MTA, 1997, J CONTROL RELEASE, V48, P47
[9]
Hydrogels: from controlled release to pH-responsive drug delivery [J].
Gupta, P ;
Vermani, K ;
Garg, S .
DRUG DISCOVERY TODAY, 2002, 7 (10) :569-579
[10]
Hydrogel nanoparticles in drug delivery [J].
Hamidi, Mehrdad ;
Azadi, Amir ;
Rafiei, Pedram .
ADVANCED DRUG DELIVERY REVIEWS, 2008, 60 (15) :1638-1649