Synthesis of well-defined macromonomers by sequential ATRP-catalytic chain transfer and copolymerization with ethyl acrylate

被引：33

作者：

Norman, J

Moratti, SC

Slark, AT

Irvine, DJ

Jackson, AT

机构：

[1] Univ Cambridge, Dept Chem, Melville Polymer Lab, Cambridge CB2 1EW, England

[2] Natl Starch, Slough SL2 5DS, Berks, England

[3] Wilton Ctr, ICI Uniqema, Middlesbrough TS90 8JE, Cleveland, England

[4] ICI Technol, Middlesbrough TS90 8JE, Cleveland, England

来源：

MACROMOLECULES | 2002年 / 35卷 / 24期

关键词：

D O I：

10.1021/ma011011v

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Polymer chains with unsaturated end groups can be produced by the addition of catalytic chain transfer agents near the end of an atom-transfer polymerization. The polymers were analyzed by MALDI-TOF, NMR, and TGA experiments to determine the degree of unsaturation with good agreement. These polymers can subsequently be used as macromonomers in copolymerizations with monomers such as ethyl acrylate.

引用

页码：8954 / 8961

页数：8

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