The structure of the decamethylborocenium cation: the most tightly-squeezed metallocene?

被引：28

作者：

Voigt, A ^{[1
]}

Filipponi, S ^{[1
]}

Macdonald, CLB ^{[1
]}

Gorden, JD ^{[1
]}

Cowley, AH ^{[1
]}

机构：

[1] Univ Texas, Dept Chem & Biochem, Austin, TX 78712 USA

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 11期

关键词：

D O I：

10.1039/b001271h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

X-Ray crystallographic analysis along with DFT calculations on the decamethylborocenium cation provide definitive structural and electronic information about this most tightly-squeezed main group metallocene-the first to adopt the elusive sigma/pi geometry in the solid state.

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页码：911 / 912

页数：2

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