Vapor-liquid equilibria and enthalpies of mixing for binary mixtures of N-methylacetamide with aniline, decane, ethylene glycol, naphthalene, phenol, and water

被引:13
作者
deHaan, A
Fischer, K
Haacke, M
Aufderhaar, O
Petri, M
Gmehling, J
机构
[1] UNIV OLDENBURG,FACHBEREICH 9,D-26111 OLDENBURG,GERMANY
[2] DSM RES BV,DEPT BASE CHEM & HYDROCARBONS,SECT REACT ENGN,NL-6160 MD GELEEN,NETHERLANDS
[3] DSM RES BV,DEPT BASE CHEM & HYDROCARBONS,UNIT OPERAT,NL-6160 MD GELEEN,NETHERLANDS
关键词
D O I
10.1021/je970031i
中图分类号
O414.1 [热力学];
学科分类号
摘要
Isothermal P-x data, isobaric T-x-y data, and enthalpies of mixing were measured for the binary systems of N-methylacetamide + aniline, decane, naphthalene, phenol, water, or ethylene glycol using a static apparatus, a Swietoslawski-ebulliometer, an isothermal flow calorimeter, and a Tian-Calvet batch calorimeter. The experimental data were correlated with the help of the NRTL or the UNIQUAC model, for which temperature dependent interaction parameters were fitted simultaneously to VLE and H-E data.
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页码:875 / 881
页数:7
相关论文
共 16 条
[1]  
AIM K, 1996, IN PRESS FLUID PHASE
[2]  
[Anonymous], 1963, RECENT PROGR MICROCA
[3]   Vapor-liquid equilibria and excess enthalpies for binary mixtures of acrylonitrile with hexane, cyclohexane, benzene, toluene, 2-butanone, and acetonitrile [J].
deHaan, AB ;
Bolts, R ;
Gmehling, J .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1996, 41 (05) :1155-1159
[4]   Vapor-liquid equilibria and excess enthalpies for binary mixtures of N-methylacetamide with 1-octene, dipropylamine, triethylamine, pyridine, and methanol at 125 degrees C [J].
deHaan, AB ;
Fischer, K ;
Haacke, M ;
Gmehling, J .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1997, 42 (03) :597-602
[5]   Excess enthalpies for various binary mixtures with N-methylacetamide or acetic anhydride [J].
deHaan, AB ;
Gmehling, J .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1996, 41 (03) :474-478
[6]   VAPOR-LIQUID-EQUILIBRIA AND EXCESS-ENTHALPIES FOR OCTANE PLUS N-METHYLACETAMIDE, CYCLOOCTANE PLUS N-METHYLACETAMIDE, AND OCTANE PLUS ACETIC-ANHYDRIDE AT 125 DEGREES-C [J].
DEHAAN, AB ;
HEINE, A ;
FISCHER, K ;
GMEHLING, J .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1995, 40 (06) :1228-1232
[7]   P-X AND GAMMA-INFINITY DATA FOR THE DIFFERENT BINARY BUTANOL-WATER SYSTEMS AT 50-DEGREES-C [J].
FISCHER, K ;
GMEHLING, J .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1994, 39 (02) :309-315
[8]   VAPOR-LIQUID EQUILIBRIA FROM TOTAL PRESSURE MEASUREMENTS - NEW APPARATUS [J].
GIBBS, RE ;
VANNESS, HC .
INDUSTRIAL & ENGINEERING CHEMISTRY FUNDAMENTALS, 1972, 11 (03) :410-&
[9]   EXCESS-ENTHALPIES FOR 1,1,1-TRICHLOROETHANE WITH ALKANES, KETONES, AND ESTERS [J].
GMEHLING, J .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1993, 38 (01) :143-146
[10]   A MODIFIED UNIFAC MODEL .2. PRESENT PARAMETER MATRIX AND RESULTS FOR DIFFERENT THERMODYNAMIC PROPERTIES [J].
GMEHLING, J ;
LI, JD ;
SCHILLER, M .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1993, 32 (01) :178-193