Structural and morphological control of cationic surfactant-templated mesoporous silica

被引：398

作者：

Lin, HP

Mou, CY ^{[1
]}

机构：

[1] Natl Taiwan Univ, Dept Chem, Taipei 106, Taiwan

[2] Natl Taiwan Univ, Ctr Condensed Matter Sci, Taipei 106, Taiwan

[3] Acad Sinica, Inst Chem, Taipei 115, Taiwan

来源：

ACCOUNTS OF CHEMICAL RESEARCH | 2002年 / 35卷 / 11期

关键词：

D O I：

10.1021/ar000074f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Micelle-templated mesoporous silica materials are rapidly becoming important in many fields of chemistry for hosting reactants or catalysts in confined space, Fine control of the pore size, wall structure, surface functionalization, defects, and morphology is needed for fine-tuning the pores as nanoreactors. We review the physical chemistry of solution silicate species and surfactants in the synthesis of mesoporous silicas. Controls in surfactant packing and liquid crystalline phase transformation can lead to various tailored synthesis strategies. Postsynthesis treatments further make more stable mesoporous materials.

引用

页码：927 / 935

页数：9

共 58 条

[51] A reliable synthesis of cubic mesoporous MCM-48 molecular sieve [J].