Recent developments in Li-ion prismatic cells

被引:9
作者
Cousseau, Jean-Francois
Siret, Clemence
Biensan, Philippe
Broussely, Michel
机构
[1] Saft Specialty Battery Grp, F-86000 Poitiers 9, France
[2] Saft Direct Rech, Bordeaux 33074, France
关键词
lithium ion; prismatic; graphite; low temperature;
D O I
10.1016/j.jpowsour.2005.02.095
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The development of new materials is required to improve the energy density of Li-ion batteries. A new graphite type with optimised physical-chemical characteristics has been studied and developed to improve negative electrode performance. Lithium ion charge and discharge acceptance have been improved by the enhanced intrinsic properties of the material. The new material has higher efficiency electrode porosity/tortuosity, and increases electrical conductivity. This allows better charge performance at low temperatures and discharge performance at high rates. Combined with an optimised electrolyte composition, it also gives low and reproducible fading, good discharge performance in very low temperature conditions, and long term storage at high temperatures. Due to this and other design modifications that will be discussed, a 22% improvement in energy density is obtained in the new generation of Saft Li-ion medium prismatic cells (MP). (c) 2005 Published by Elsevier B.V.
引用
收藏
页码:790 / 796
页数:7
相关论文
共 14 条
[1]  
BIESAN P, 1994, Patent No. 9404889
[2]   Properties of large Li ion cells using a nickel based mixed oxide [J].
Broussely, A ;
Blanchard, P ;
Biensan, P ;
Planchat, JP ;
Nechev, K ;
Staniewicz, RJ .
JOURNAL OF POWER SOURCES, 2003, 119 :859-864
[3]  
BROUSSELY M, 2002, ADV LITHIUM ION BATT, V13, P394
[4]   Carbon materials for lithium-ion rechargeable batteries [J].
Flandrois, S ;
Simon, B .
CARBON, 1999, 37 (02) :165-180
[5]   Effect of graphite crystal structure on lithium electrochemical intercalation [J].
Guerin, K ;
Fevrier-Bouvier, A ;
Flandrois, S ;
Couzi, M ;
Simon, B ;
Biensan, P .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (10) :3660-3665
[6]   The complex electrochemistry of graphite electrodes in lithium-ion batteries [J].
Novák, P ;
Joho, F ;
Lanz, M ;
Rykart, B ;
Panitz, JC ;
Alliata, D ;
Kötz, R ;
Haas, O .
JOURNAL OF POWER SOURCES, 2001, 97-8 :39-46
[7]   Factors affecting rate capability of graphite electrodes for lithium-ion batteries [J].
Sawai, K ;
Ohzuku, T .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (06) :A674-A678
[8]   Cycling performance of low-cost lithium ion batteries with natural graphite and LiFePO4 [J].
Shim, J ;
Striebel, KA .
JOURNAL OF POWER SOURCES, 2003, 119 :955-958
[9]  
SIMON B, 1994, Patent No. 5626981
[10]  
Simon B., 1997, ECS M ABSTR PAR SEPT, V97-2, P184